AMI is so cool! Twilight sees a lot of herself in Ami: the sanctuary in books, a huge amount of curiosity for learning, and being in the library all the time. Twilight likes how helpful Ami is and pretty much considers her a friend already. Expect study parties with these two in the future.
BILBO is an odd duck and Twilight can't figure out what's not human about him, but he seems like a kind and adventurous fellow egghead, and the world doesn't have enough of those.
DARIA can be too pessimistic for Twilight's taste occasionally, but Twi can tell that Daria's heart is in the right place, and anypony who hangs out in the library can't be all bad, so Twilight is cautiously friendly towards her. (Well, as cautious as Twilight can be, anyway.)
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BILBO is an odd duck and Twilight can't figure out what's not human about him, but he seems like a kind and adventurous fellow egghead, and the world doesn't have enough of those.
DARIA can be too pessimistic for Twilight's taste occasionally, but Twi can tell that Daria's heart is in the right place, and anypony who hangs out in the library can't be all bad, so Twilight is cautiously friendly towards her. (Well, as cautious as Twilight can be, anyway.)